Brad Pitt and Angelina Jolie

celebrity couples

What did people think was going to happen when the two sexiest movie stars on the planet filmed Mr. and Mrs. Smith (2005) together? Pitt was famously married to girl-next-door Jennifer Aniston, but the chemistry between him and Jolie was palpable. Shortly after wrapping, Brad took Jennifer on a now-famous, farewell beach vacay…and dumped her. Eight years, thousands of tabloid covers, and roughly nineteen children later, Brangelina’s still going strong. And Aniston stans continue to call for Angelina’s head.